Part of the Oxford Instruments Group
Expand
NanoAnalysis | Blog
Find small and discrete phases in your sample

29thJuly 2020 | Author: Anthony Hyde

Acquiring X-Ray maps is a great way to find out what elements are present in your sample and how they are distributed. With a modern EDS system, you can simply press a button to start acquisition. Element peaks are identified, and their associated X-ray maps are displayed automatically. Unfortunately, because the sum spectrum can sometimes be dominated by larger phases, unless you know that your sample has very small and discrete phases, then it is likely that these phases will be missed.

Spectrum Examiner is designed to find these small phases by analysing AZtec’s SmartMaps in detail and highlighting interesting energy regions in the sum spectrum where there is a significant variation in pixel counts.

To illustrate this, we can see a mapping analysis of a mineral sample below. AZtec automatically identified the individual peaks and displayed the corresponding X-Ray maps.

A first glance at the sum spectra reveals no issues, so it is likely the analyst would think that they have a representative data set from this area.

If we activate the Spectrum Examiner button, we will see a red overlay on the spectrum. This overlay highlights interesting regions in the sum spectrum (peaks in the overlay). All a user has to do is look for a peak in the red overlay that doesn’t have a corresponding peak in the sum spectrum.

Once such a peak has been identified, the user then clicks on this region to reveal the possible ‘Candidate Elements’ that could be responsible for the peak.

In this case, the most likely candidate for the peak is Phosphorus. By clicking on the Phosphorus label, AZtec automatically displays the corresponding X-Ray map and we can immediately see that there are small concentrations of P that were missed in the initial inspection.

Reconstructing a spectrum from one of these phases reveals significant levels of Ca and P.

Spectrum Examiner is a quick, easy, and powerful tool that takes the hard work out of ‘Finding a Needle in a Haystack.” Discover more from your sample now and book a demo for AZtecLive.

Book a Demo
Ask me a question Anthony Hyde

Anthony Hyde

EDS Product Manager

Join our Mailing List

We send out monthly newsletters keeping you up to date with our latest developments such as webinars, new application notes and product updates.